Product ID:TIBC STOCK IRON SATURATING SOLUTION 680362
MSDS Date:11/05/1986
FSC:6850
NIIN:00N012050
MSDS Number: BHTPN

Emergency Phone: 800-441-3637

Info Phone: 302-992-4132

Preparer: KEN WOODLIN

Cage: 18897

Telephone: 800-441-9861

Cage: 18897

CITRIC ACID

CAS: 77-92-9

RTECS: GE7350000

Fraction By Weight: 1-2%

OSHA PEL N/K

ACGIH TLV: N/K

LD50 LC50 Mixture:ORAL RAT LD50; 11700 MG/KG CIRTIC ACID
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: UNDER NORMAL CONDITIONS, LIQUID
IS NOT EXPECTED TO PRESENT A HAZARD. MIST OR AEROSOL MAY CAUSE
BURNING OF NOSE, THROAT, AND MUCOUS MEMBRANES, HEADACHE, COUGH,
DIZZINESS, OR DIFFICULTY BREATHING . SKIN: FOR CITRIC
ACID-SKIN-RABBIT IRRIT; 500 MG/24 HOURS, MOD. MAY CAUSE IRRIT W/
DISCOMFORT, RASH.(EFFETS OF OVEREXP)
Explanation of Carcinogenicity:NONE OF THE COMPONENTS IN THIS CHEMICAL
IS LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN (MFR).
Effects of Overexposure:HLTH HAZ: EYE: MAY CAUSE IRRIT W/ DISCOMFORT,
TEARING, OR BLURRING OF VISION. MAY CAUSE BURNS ON PROLONGED
CONTACT. INGEST: MINIMALLY TOXIC. TARGET ORGANS: EYES. EFFECTS OF
RPTD EXPOSURE: NO REPORTS O F HUMAN SENSIT. AVOID LONG-TERM
OVEREXPOS TO TOOTH ENAMEL; MAY CAUSE DAMAGE TO TOOTH ENAMEL. ANIMAL
TESTING (SUP DATA)
Medical Cond Aggravated by Exposure:NO INFORMATION FOUND (MFR)

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP,
PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL PHYSICIAN. SKIN: FLUSH WITH WATER. EYE: IMMEDIATELY FLUSH EYES
WIT H PLENTY OF WATER FOR AT LEAST 15 MINUTES. CALL A PHYSICIAN.
INGEST: NO SPECIFIC INTERVENTION IS INDICATED AS THE COMPOUND IS
NOT LIKELY TO BE HAZ BY INGEST. HOWEVER, CONSULT A PHYSICIAN IF
NECESSARY.

Flash Point:N/K
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:WATER, WATER SPRAY, WATER FOG, CHEMICAL FOAM,
ALCOHOL FOAM, DRY POWDER (SAND), DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:EVACUATE PERSONNEL TO A SAFE AREA. KEEP
PERSONNEL REMOVED AND UPWIND OF FIRE.
Unusual Fire/Explosion Hazard:NO INFORMATION AVAILABLE (MFR)

Spill Release Procedures:REVIEW FIRE AND EXPLOSION HAZARDS AND SAFETY
PRECAUTIONS BEFORE PRECEEDING WITH CLEAN UP. USE APPROPRIATE
PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN UP. ABSORB ONTO
ABSORBENT MATERIAL, SEAL IN PLASTIC BAG.
Neutralizing Agent:SODIUM HYDROXIDE

Handling and Storage Precautions:PER PRODUCT INSERT SHEET
Other Precautions:DO NOT MIX WITH INCOMPATABLES LISTED UNDER HAZARDOUS
REACTIVITY. PREVENT CONTACT WITH BRASS OR COPPER. REFER TO
EXPIRATION DATE ON KIT LABEL.

Respiratory Protection:NONE (MFR). NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN ( ).
Ventilation:NONE (MFR). CONSULT LOCAL SAFETY/HEALTH AUTHORITIES IF
ADDITIONAL GUIDANCE IS NECESSARY .
Protective Gloves:RECOMMEND IF CUT OR OPEN WOUNDS ON HANDS
Eye Protection:CHEMICAL WORKERS GOGGLES
Other Protective Equipment:N/K
Work Hygienic Practices:OBSERVE GOOD WORK HYGIENIC PRACTICES
Supplemental Safety and Health
VAPOR DENSITY: SIMILAR TO WATER. VAPOR PRESSURE: SIMILAR TO WATER. EFTS
OF OVEREXPOS: INDICATES THAT THIS COMPOUND DOES NOT HAVE
EMBRYOTOXIC, OR REPRODUCTIVE EFFECTS.

HCC:C1
Boiling Pt:B.P. Text:212 F;100 C
Melt/Freeze Pt:M.P/F.P Text:32 F; 0 C
Decomp Temp:Decomp Text:N/K
Vapor Pres:SUP DATA
Vapor Density:SUP DATA
Spec Gravity:1.0
pH:1.0
Evaporation Rate & Reference:SIMILAR TO WATER
Solubility in Water:100 WT% @ 20 C
Appearance and Odor:YELLOW LIQUID, NO ODOR
Percent Volatiles by Volume:AQ

Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/ ALKALINE EARTH CARBONATES, ACETATES, SULFIDES, STRONG
BASES, ALKALI METAL, ORGANIC ACIDS, SULFUR OXIDES.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:DECOMPOSES WITH HEAT. REFER TO
EXPIRATION DATE ON THE LABEL. MAY DECOMPOSE WITH TIME (MFR).

Waste Disposal Methods:FOR <1 LITER, FLUSH TO ACID DRAIN W/ EXCESS
WATER. FOR LARGER QUANTITIES, NEUTRALIZE WITH SODIUM HYDROXIDE,
FLUSH TO DRAIN. DISPOSE PER LOCAL GUIDELINES (MFR). DISPOSAL MUST
BE IN ACCORDANCE WITH FEDE RAL, STATE AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.